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Which combination of the following statements is correct?                                                     

P: A gas cools upon expansion only when its Joule-Thomson Co-efficient is positive in the temperature range of expansion.

Q. For a system undergoing a process, its entropy remains constant only when the process is reversible

R. The work done by a closed system in an adiabatic process is a point function.

S. A liqauid expand upon freezing when the slope of its fusion curve on Pressure Temperature diagram is negative

      (a) R and S                                                          (b) P and Q

      (c) Q, R and S                                                     (d) P, Q and R

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